Suppose you have a primary key containing a nullable column Kn.
If you want to have a second row rejected on the ground that in that second row, Kn is null and the table already contains a row with Kn null, then you are actually requiring that the system would treat the comparison "row1.Kn = row2.Kn" as giving TRUE (because you somehow want the system to detect that the key values in those rows are indeed equal). However, this comparison boils down to the comparison "null = null", and the standard already explicitly specifies that null doesn't compare equal to anything, including itself.
To allow for what you want, would thus amount to SQL deviating from its own principles regarding the treatment of null. There are innumerable inconsistencies in SQL, but this particular one never got past the committee.
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